What is the function of buffer in EDTA titration?
A buffer solution is used in EDTA titration because it resists the change in pH. This is because all the reactions between the metal ions and EDTA are pH-dependent.
What is the role of EDTA in determination of hardness of water?
In the determination of water hardness, ethylene- diaminetetraacetic acid (EDTA) is used as the titrant that complexes Ca2+ and Mg2+ ions. This color change signals the end point, as it takes place when the EDTA, after complexing all of the unbound Ca2+ and Mg2+ ions, removes the Mg2+ ion bound to the indicator.
Why do we use EDTA solutions?
EDTA is often used as the disodium salt, Na2H2Y . Carrying out the reaction in a basic buffer solution removes the H+ as it is formed. This moves the position of equilibrium to the right and favours formation of the complex (Le Châtelier’s Principle). Also, for EDTA, pKa4 = 10.26.
What type of buffer is used in EDTA titration?
Hardness is determined by titrating with EDTA at a buffered pH of 10. Calmagite is used as an indicator.
Why EBT is used in complexometric titration?
Eriochrome black T is used as an indicator for complexometric titrations because it forms a colored complex in its protonated form with calcium,…
What is the principle involved in complexometric titration?
An indicator capable of producing an unambiguous color change is usually used to detect the end-point of the titration. Complexometric titration are those reactions where a simple ion is transformed into a complex ion and the equivalence point is determined by using metal indicators or electrometrically.
How does EDTA titration work?
An EDTA titration can be used to determine the concentration of metal ions in a substance. For example the Nickel content in a salt. In this experiment the indicator used is murexide indicator which binds less strongly to the Nickel ions than EDTA so when the reaction is complete (all the Nickel is used up)…
How to find molarity of EDTA?
Calculate the average molarity of the EDTA solution from the concentration of the calcium chloride solution and the volume of EDTA used to titrate . Determine the unknown calcium concentration in a sample of water. Pipet 50 mL portions of unknown water into three 250 mL Erlenmeyer flasks.
What is the formula for titration?
Titration Formula. V acid = Volume of the acid M base = Molarity of the base V base = Volume of the base If the titrant and analyte have a 1:1 mole ratio, the equation above can be used to determine the unknown concentration, if the ratio is not 1:1 then a modified version should be used.
What is EDTA, acid or basic?
Ethylenediaminetetraacetic acid (EDTA), also known by several other names, is a chemical used for both industrial and medical purposes. It was synthesized for the first time in 1935 by Ferdinand Münz. It is an aminopolycarboxylic acid and a colorless, water-soluble solid.