What is EDTA complex?
EDTA or ethylenediaminetetraacetic acid is a novel molecule for complexing metal ions. It is a polyprotic acid containing four carboxylic acid groups (acidic hydrogens are red) and two amine groups with lone pair electrons (green dots). The classic structural formula is given below.
How does EDTA chelate calcium?
It can form four or six bonds with a metal ion, and it forms chelates with both transition-metal ions and main-group ions. EDTA is frequently used in soaps and detergents, because it forms a complexes with calcium and magnesium ions. The EDTA binds to them, sequestering them and preventing their interference.
Why EDTA complex is stable than EBT complex?
EDTA is insoluble in water at low pH because H4Y is predominant in that pH (less than 2). With increasing the pH, each hydrogen ion in the carboxyl groups of EDTA will start to dissociate. As we need Y4- to react with the metal ions present in the titration solution, we use pH 10 buffer such as ammonium chloride.
Why is the EDTA complex formed in solution?
EDTA is a hexa dentate ligand capable of forming chelates/ complexes with almost all metals easily and their stability depend on the pH of the solution so that titration can be carried out preferentially with one metal ion in presence of the other, in solution.
Why is EDTA insoluble in water?
The carboxyl groups of EDTA are not dissociated at low pH. Undissociated carboxyls (COOH) have no charge because the hydrogen is covalently bound and therefore acid EDTA is almost insoluble in water.
Which is more stable mg EDTA or Mg EBT?
While the Mg-EDTA complex is colorless, Mg-EBT complex is of wine-red color (and more stable than the former). (Note: Thus the wine-red color of the solution in conical is due to Mg-EBT complex.)
Why is EDTA used in water hardness?
In the determination of water hardness, ethylene- diaminetetraacetic acid (EDTA) is used as the titrant that complexes Ca2+ and Mg2+ ions. This color change signals the end point, as it takes place when the EDTA, after complexing all of the unbound Ca2+ and Mg2+ ions, removes the Mg2+ ion bound to the indicator.
Why EDTA is soluble in water?
The carboxyl groups of EDTA are not dissociated at low pH. Dissociated EDTA is ionic and thus water soluble. Note that there are four carboxyls in EDTA molecule, “each” dissociates in different pH – pKa values are 2.0, 2.7, 6.2 and 10.3 (pKa means pH at which half of the carboxyls are dissociated).
How soluble is EDTA?
This product is slowly soluble in water at room temperature up to 0.26 M, which is approximately 96 mg in a final volume of 1 ml. The pH of this solution will be in the range of 4 to 6.
Which form of EDTA is soluble in water?
EDTA salts are more soluble in water as the pH increases: the more EDTA there is in the salt form, the higher the pH of a water solution, and therefore, the higher the room temperature solubility. This can be achieved by a gradual addition of concentrated sodium hydroxide solution to the EDTA solution.
What is the solubility of EDTA at room temperature?
solution will be in the range of 4 to 6. EDTA salts are more soluble in water as the pH increases: the more EDTA there is in the salt form, the higher the pH of a water solution, and therefore, the higher the room temperature solubility. This can be achieved by a gradual addition of concentrated sodium hydroxide solution to the EDTA solution.
How do you determine the calcium content in EDTA titration?
Calcium can be determined by EDTA titration in solution of 0.1 M sodium hydroxide (pH 12-13) against murexide. Presence of ammonium salts is undesired, as they lower pH and make end point less sharp. To get rid of ammonia, solution can be heated after NaOH was added.
How does EDTA act as a hard water chelating agent?
EDTA itself is quite soluble, and is quite a strong chelating agent- especially for calcium and other hard water ions. As such it has the ability to bind calcium ions into solution in circumstances when they would otherwise begin to precipitate out.
How to dissolve edta-2na in aqueous solution?
First, dissolve EDTA-2Na then adjust the pH. The range of pH in this application is + _ 0.2, so don’t worry about the exact 8.0 pH. Two preliminary publications describe the reactions of EDTA at elevated temperatures in aqueous solution (1, 2).