Why is EDTA form stable complex?
EDTA-metal ligand complex The oxygens in the four carboxylic groups deprotonate, and one of the lone electron pairs left on these is available to form a coordination bond with the metal ion. The complexes formed are very strong because they form stable five-membered rings, i.e. chelates.
What is CA EDTA complex?
Figure 6 presents the molecular structure of the Ca-EDTA complex. In the complex, EDTA acts as a hexadentate unit by wrapping itself around the metal ion with four oxygen atoms and two nitrogen atoms and forms several five-member chelate rings. …
Why is EDTA an appropriate titrant for the determination of water hardness?
In the determination of water hardness, ethylene- diaminetetraacetic acid (EDTA) is used as the titrant that complexes Ca2+ and Mg2+ ions. This color change signals the end point, as it takes place when the EDTA, after complexing all of the unbound Ca2+ and Mg2+ ions, removes the Mg2+ ion bound to the indicator.
How does EDTA titration work?
The most common indicators in complexometric titrations are organic dyes which function by forming a colored complex with the metal ion being titrated. During the reaction, EDTA replaces the indicator to form a more stable complex with metal and when the reaction is completed the change for the color is observed.
How does EDTA react with calcium?
The method uses a very large molecule called EDTA which forms a complex with calcium ions. EDTA stands for ethylenediaminetetraacetic acid. As a result, when the calcium ion–PR complex is titrated with EDTA the Ca2+ ions react to form a stronger complex with the EDTA.
What type of complex does EDTA form?
EDTA forms an octahedral complex with most 2+ metal cations, M2+, in aqueous solution.
Why does Ca2+ form more stable complex with EDTA than Mg2+?
Chemistry: Why does Ca2+ form a more stable complex with EDTA than Mg2+? Calcium ion has larger size than magnesium ion . Fajans rule states that larger anion is stabilised by larger cation.Hence calcium is more stable with EDTA4- . Also the high negative charge is distributed more on larger cation.
Is EDTA a stable complex?
EDTA is a hexa-dentate ligand and thus ‘wraps’ around a metal like an alien face-hugger around a human head. Once this ligand ‘has locked on’ (chelating effect) a metal it forms a VERY stable complex!
What does EDTA react with for titration?
For the titration, the sample solution containing the calcium and magnesium ions is reacted with an excess of EDTA. One may also ask, what is the role of EDTA?
What is the role of EDTA in the determination of calcium?
EDTA is used extensively in the analysis of blood. It is an anticoagulant for blood samples for CBC/FBEs, where the EDTA chelates the calcium present in the blood specimen, arresting the coagulation process and preserving blood cell morphology. Similarly, it is asked, what is the role of NaOH in the determination of calcium in water using EDTA?