What is C3S C2S and C3A?
The ratio of C3S to C2S helps to determine how fast the cement will set, with faster setting occurring with higher C3S contents. Lower C3A content promotes resistance to sulfates. Higher amounts of ferrite lead to slower hydration.
What are the roles of C3A and C4AF in cement hydration?
Ferrite Phase (C4AF) forms the same hydration products as C3A, with or without gypsum. The reaction is slow and is decreased further by gypsum. If the iron oxide content is increased, the reaction is slower. Experience has shown cements low in C3A and high in C4AF are sulfate resistant.
What is C3S in clinker?
Alite (C3S): the alite crystal is the preferred clinker phase in Portland cement clinker. The formation of alite is very complex. Alite is only formed in the presence of excess CaO, that is, at CaO/SiO2 > 1 and is thermodynamically stable above 1250°C [44].
What is C2S chemistry?
Acetylene sulfide
PubChem CID | 86012988 |
---|---|
Structure | Find Similar Structures |
Molecular Formula | C2S |
Synonyms | acetylene sulfide |
Molecular Weight | 56.09 |
What is the function of C3a in cement?
Tricalcium aluminate (C3A) is mostly related to the heat of hydration. It releases large amount of heat during the first few days of hardening which generally results in early age cracking. Cements with high content of C3A are not suitable for mass concreting and are better to be mixed with fly ash.
What is the role of C3a in cement?
Tricalcium aluminate (C3A) is one of the main constituents of Portland cement. Gypsum is added to regulate this reaction and preserves the workability of the cement paste at early ages. The understanding of the C3A-gypsum reaction is therefore crucial for the comprehension of the early hydration of cement.
What is the role of c4af in the setting time of cement?
Ferrite, C4AF: This is a fluxing agent which reduces the melting temperature of the raw materials in the kiln (from 3,000o F to 2,600o F). It hydrates rapidly, but does not contribute much to strength of the cement paste.
How is C3S formed?
Sulphate in stoichiometric excess of alkalis in clinker will be present as calcium sulphate, CaSO4. Phosphate above 0.5 per cent in clinker leads to progressive decomposition of C3S to form a solid solution of tricalcium phosphate and C2S.
What is the chemical name of C3A?
Tricalcium aluminate (C3A) is one of the main constituents of Portland cement.