What happens when pH is not maintained in complexometric titration?
EDTA is often used as the disodium salt, Na2H2Y . Carrying out the reaction in a basic buffer solution removes the H+ as it is formed. Thus, if the solution is buffered to about pH 10.3, most of the EDTA will exist as Y4- ions. The metal ions will not have to remove the hydrogen ions from H2Y2- .
Which base is used to maintain the pH of complexometric titration?
EDTA Competes With Other Ligands To maintain a constant pH during a complexation titration we usually add a buffering agent. If one of the buffer’s components is a ligand that binds Cd2+, then EDTA must compete with the ligand for Cd2+.
Is EDTA affected by pH?
EDTA is insoluble in water but dissolve with the increment of pH.
Why do we maintain pH in water hardness?
Hard water (high mineral content) is usually high in pH. Soft water (low mineral) is usually low in pH. The mineral in hard water will act as a buffer which will reduce the amount of acid in the water. The resulting water will be more alkaline and higher in pH.
What could be the role of complexometric titration?
Complexometric titration (sometimes chelatometry) is a form of volumetric analysis in which the formation of a colored complex is used to indicate the end point of a titration. Complexometric titrations are particularly useful for the determination of a mixture of different metal ions in solution.
Why is buffer required in EDTA titration?
A buffer solution is used in EDTA titration because it resists the change in pH. This is because all the reactions between the metal ions and EDTA are pH-dependent.
Why is complexometric titration necessary in pharmaceutical analysis?
Complexometric titrations are particularly useful for the determination of a mixture of different metal ions in solution. An indicator capable of producing an unambiguous color change is usually used to detect the end-point of the titration.
What is the pH of EDTA titration?
The EDTA titration method can be used to measure the calcium concentrations up to 160 ppm in the pH range of 0 to 7.
What is the difference between acid base titration and complexometric titration?
In acid-base titrations, the pH usually is the dependent variable to be measured; in complexometric titrations, however, we use the formation of a complex as an end point indication. Any change in pH can influence the outcome of the complex formation.
How to prevent a pH change during the titration?
Thus, to prevent a pH change during the titration, the solution must be adequately buffered. A titration curve in complexometric titrations shows relationship between pMe and the titrant volume. The change of the pMe in the end point region increases with the increase of the stability constant of the formed complex.
What is the pH for complexometric titration of Fe and Zn?
Thus if you are titrating Fe using salicylic acid, it needs to be in the acid range at about pH 2 to 3. On the other hand to use eriorchrome Blue Black R for Zn, There are two parts to this. A complexometric titration works by a complexing agent (EDTA) clustering around a metal ion.
What is EDTA in a complexometric titration?
A complexometric titration uses the formation of a coloured complex to indicate the endpoint. EDTA, often written as H4Y, is a common ligand in complexometric titrations. It has four carboxyl groups and two amine groups that can act as electron pair donors (Lewis bases). EDTA is often used as the disodium salt, Na2H2Y.